1.14.13.84: 4-hydroxyacetophenone monooxygenase
This is an abbreviated version!
For detailed information about 4-hydroxyacetophenone monooxygenase, go to the full flat file.
Word Map on EC 1.14.13.84
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1.14.13.84
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baeyer-villiger
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fluorescens
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ketones
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bvmos
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acetophenones
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cyclohexanone
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nadph-dependent
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biocatalytic
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putida
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enantioselectivity
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resin
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base-catalysed
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stabilised
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ring-substituted
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characterise
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fad
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flavoproteins
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synthesis
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4-fluorophenol
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fluorophenyl
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fluoride
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flavin-containing
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synthons
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4-fluorocatechol
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sulfides
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lactones
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fluorinated
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noncovalent
- 1.14.13.84
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baeyer-villiger
- fluorescens
- ketones
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bvmos
- acetophenones
- cyclohexanone
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nadph-dependent
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biocatalytic
- putida
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enantioselectivity
- resin
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base-catalysed
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stabilised
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ring-substituted
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characterise
- fad
- flavoproteins
- synthesis
- 4-fluorophenol
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fluorophenyl
- fluoride
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flavin-containing
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synthons
- 4-fluorocatechol
- sulfides
- lactones
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fluorinated
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noncovalent
Reaction
Synonyms
4-hydroxyacetophenone monooxygenase, arylketone monooxygenase, Baeyer-Villiger monooxygenase, hAPA, HAPMO, More, oxygenase, 4-hydroxyacetophenone mono-
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 1.14.13.84 - 4-hydroxyacetophenone monooxygenase
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REACTION DIAGRAM
4-hydroxyphenyl acetate + NADP+ + H2O
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(4-hydroxyphenyl)ethan-1-one + NADPH + O2
4-hydroxyphenyl acetate + NADP+ + H2O
1 unit enzyme oxidizes 1 micromol substrate to product per minute at pH 9.0, 25°C in the presence of NADPH
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(4-hydroxyphenyl)ethan-1-one + NADPH + O2
4-hydroxyphenyl acetate + NADP+ + H2O
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(4-hydroxyphenyl)ethan-1-one + NADPH + O2
4-hydroxyphenyl acetate + NADP+ + H2O
1 unit enzyme oxidizes 1 micromol substrate to product per minute at pH 9.0, 25°C in the presence of NADPH
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4-hydroxyphenyl acetate + NADP+ + H2O
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4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
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physiological substrate
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?
4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
catalyzes the first step in the degradation of 4-hydroxyacetophenone
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?
4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
the enzyme catalyzes the first committed step in th 4-hydroxyacetophenone catabolism, pathway overview
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4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
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physiological substrate
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?
4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
catalyzes the first step in the degradation of 4-hydroxyacetophenone
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?
4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
the enzyme catalyzes the first committed step in th 4-hydroxyacetophenone catabolism, pathway overview
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4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
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involved in the Baeyer-Villiger oxygenation of 4-hydroxyacetophenone, catalyzes one of the steps in the catabolism of 4-ethylphenol, inducible enzyme
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4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
and related cyclic aliphatic ketones, no activity with NADH as cofactor
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4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
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involved in the Baeyer-Villiger oxygenation of 4-hydroxyacetophenone, catalyzes one of the steps in the catabolism of 4-ethylphenol, inducible enzyme
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?
4-hydroxyacetophenone + NADPH + H+ + O2
4-hydroxyphenyl acetate + NADP+ + H2O
and related cyclic aliphatic ketones, no activity with NADH as cofactor
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?