1.3.7.13: 3,8-divinyl protochlorophyllide a 8-vinyl-reductase (ferredoxin)
This is an abbreviated version!
For detailed information about 3,8-divinyl protochlorophyllide a 8-vinyl-reductase (ferredoxin), go to the full flat file.
Word Map on EC 1.3.7.13
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1.3.7.13
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light-dependent
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nadph-protochlorophyllide
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cyanobacterial
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illumination
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etioplasts
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dark-grown
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1.6.99.1
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angiosperms
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prolamellar
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leptolyngbya
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synechocystis
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boryana
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penultimate
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phototrophs
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plb
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dark-operative
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monocot
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photoactive
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light-grown
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bacteriochlorophylls
- 1.3.7.13
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light-dependent
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nadph-protochlorophyllide
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cyanobacterial
- illumination
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etioplasts
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dark-grown
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1.6.99.1
- angiosperms
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prolamellar
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leptolyngbya
- synechocystis
- boryana
-
penultimate
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phototrophs
- plb
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dark-operative
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monocot
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photoactive
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light-grown
- bacteriochlorophylls
Reaction
+ 2 oxidized ferredoxin [iron-sulfur] cluster = + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
Synonyms
3,8-divinyl chlorophyllide reductase, 8-vinyl reductase, 8V reductase, 8VR, AM1_2849, bciB, C8 vinyl reductase, C8-vinyl reductase, C8-vinyl-reductase, chlorophyllide a oxidoreductase, Ctha_1208, cvrA, cyano-type divinyl chlorophyllide a 8-vinyl-reductase, DVR, F-DVR, Fd-dependent DVR, ferredoxin-dependent 8-vinyl-protochlorophyllide reductase, frhB, nucleoside-diphosphate-sugar epimerase, PChlide reductase, RSP_3070, Slr1923, Slr1923 potein, SyF-DVR
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 1.3.7.13 - 3,8-divinyl protochlorophyllide a 8-vinyl-reductase (ferredoxin)
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REACTION DIAGRAM
3,8-divinyl chlorophyll a + reduced ferredoxin [iron-sulfur] cluster + H+
chlorophyll a + oxidized ferredoxin [iron-sulfur] cluster
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3,8-divinyl chlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
chlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
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3,8-divinyl chlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + NADPH + H+
chlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + NADP+
preferred substrate
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3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
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3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+ + NADPH + H+
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + NADP+
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + NADPH + H+
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + NADP+
8-vinyl protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
chlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster
8-vinyl chlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
protochlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster
8-vinyl protochlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + NADP+
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3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+ + NADPH + H+
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + NADP+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + NADP+
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3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + NADPH + H+
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + NADP+
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?
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + NADPH + H+
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + NADP+
is reduced only under conditions in which this pigment accumulates as a result of perturbed formation of chlorophyllide
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8-vinyl chlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
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chlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster
8-vinyl chlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
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?
chlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster
8-vinyl chlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
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chlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster
8-vinyl chlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
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?
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
Pelodictyon clathratiforme DSM 5477
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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?
protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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protochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster
3,8-divinyl protochlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + H+
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although the native BciB is able to reduce the 8V group of Pchlide, the preferred substrate for this enzyme is 8V Chlide, with only a small amount of 8E Pchlide detected in the wild-type when grown under pigment accumulating conditions
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additional information
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cyanobacterial 3,8-divinyl chlorophyllide reductase (DVR) is a Chl biosynthetic enzyme that has many promiscuous activities besides the 3,8-divinyl chlorophyllide reductase activity, e.g. 7-hydroxymethyl chlorophyll a reductase activity. The Chl c2 to Chl c1 conversion is existent in cyanobacteria as a promiscuous activity of F-DVR. Chl c1 is synthesized by the reduction of the 8-vinyl group of Chl c2 or Chl c1 is synthesized from monovinyl-protochlorophyllide by the dehydrogenase
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