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Information on EC 1.13.11.53 - acireductone dioxygenase (Ni2+-requiring)

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IUBMB Comments
Requires Ni2+. If iron(II) is bound instead of Ni2+, the reaction catalysed by EC 1.13.11.54, acireductone dioxygenase [iron(II)-requiring], occurs instead . The enzyme from the bacterium Klebsiella oxytoca (formerly Klebsiella pneumoniae) ATCC strain 8724 is involved in the methionine salvage pathway.
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The expected taxonomic range for this enzyme is: Eukaryota, Bacteria
Synonyms
acireductone dioxygenase, aci-reductone dioxygenase, human aci-reductone dioxygenase 1, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
1,2-dihydroxy-5-(methylsulfanyl)pent-1-en-3-one + O2 = 3-(methylsulfanyl)propanoate + formate + CO
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