Organism | UniProt | Comment | Textmining |
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synthetic construct | - |
- |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
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additional information | a mononuclear NiII complex bearing the monoanion of 1-acetoxy-3-phenylpropane-2,3-dione as a ligand, i.e. (N,N-bis[(6-phenyl-2-pyridyl)methyl]-N-(2-pyridylmethyl)amine)Ni[PhC(O)C(O)CHOC(O)CH3]ClO4 after deprotection by the addition of NaOCH3 in methanol generates a NiII species that contains a coordinated dianionic C(1)-H acireductone. Exposure of this acireductone to O2 leads to regioselective oxidative cleavage reactivity akin to that found for the NiII-containing acireductone dioxygenase enzyme | synthetic construct | ? | - |
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