1.1.3.49: (R)-mandelonitrile oxidase

This is an abbreviated version!
For detailed information about (R)-mandelonitrile oxidase, go to the full flat file.

Reaction

(R)-mandelonitrile
+
O2
=
benzoyl cyanide
+
H2O2

Synonyms

ChuaMOX

ECTree

     1 Oxidoreductases
         1.1 Acting on the CH-OH group of donors
             1.1.3 With oxygen as acceptor
                1.1.3.49 (R)-mandelonitrile oxidase

Substrates Products

Substrates Products on EC 1.1.3.49 - (R)-mandelonitrile oxidase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(3E,5E)-2-hydroxydeca-3,5-dienenitrile + O2
(3E,5E)-2-oxodeca-3,5-dienenitrile + H2O2
show the reaction diagram
A0A173MZJ8
10% of the activity with (R)-mandelonitrile
-
-
?
(E)-2-hydroxy-4-phenylbut-3-enenitrile + O2
(3E)-2-oxo-4-phenylbut-3-enenitrile + H2O2
show the reaction diagram
A0A173MZJ8
29% of the activity with (R)-mandelonitrile
-
-
?
(R)-mandelonitrile + O2
benzoyl cyanide + H2O2
show the reaction diagram
A0A173MZJ8
-
enzyme stoichiometrically catalyzes oxygen consumption and synthesis of benzoyl cyanide and hydrogen peroxide from mandelonitrile
-
?
(R,S)-mandelonitrile + O2
benzoyl cyanide + H2O2
show the reaction diagram
A0A173MZJ8
-
-
-
?
2-(3-bromophenyl)-2-hydroxyacetonitrile + O2
(3-bromophenyl)(oxo)acetonitrile + H2O2
show the reaction diagram
A0A173MZJ8
22% of the activity with (R)-mandelonitrile
-
-
?
2-hydroxy-2-(2-methoxyphenyl)acetonitrile + O2
(2-methoxyphenyl)(oxo)acetonitrile + H2O2
show the reaction diagram
A0A173MZJ8
17% of the activity with (R)-mandelonitrile
-
-
?