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(1R)-pulegone + NADPH + H+ + O2
?
(1R,4R)-dihydrocarvone + NADPH + H+ + O2
(4R,7R)-4-isopropenyl-7-methyl-2-oxo-oxepanone + NADP+ + H2O
(1R,4S)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2
(3S)-3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
(1R,4S)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2
3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
(1R,4S)-menthone + NADPH + H+ + O2
(4R,7S)-7-isopropyl-4-methyl-2-oxo-oxepanone + NADP+ + H2O
-
76% of the activity with (1R,4R)-dihydrocarvone
-
-
?
(1S)-pulegone + NADPH + H+ + O2
?
-
51% of the activity with (1R,4R)-dihydrocarvone
-
-
?
(1S,4R)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2
(3R)-3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
-
-
-
-
?
(1S,4R)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2
3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
-
3-isopropenyl-6-oxoheptanoate is the spontaneous rearrangement product of the lactone formed by MMKMO. 88% of the activity with (1R,4R)-dihydrocarvone
-
-
?
(1S,4R)-dihydrocarvone + NADPH + H+ + O2
?
-
-
-
-
?
(1S,4R)-menthone + NADPH + H+ + O2
(4S,7R)-7-isopropyl-4-methyl-2-oxo-oxepanone + NADP+ + H2O
-
82% of the activity with (1R,4R)-dihydrocarvone
-
-
?
(1S,4R)iso-dihydrocarvone + NADPH + H+ + O2
(3S,4R)-6-isopropenyl-3-methyl-2-oxo-oxepanone + NADP+ + H2O
-
-
-
-
?
(4S)-carvone + NADPH + H+ + O2
?
-
14% of the activity with (1R,4R)-dihydrocarvone
-
-
?
1,2-cyclohexanedione + NADPH + H+ + O2
?
-
95% of the activity with (1R,4R)-dihydrocarvone
-
-
?
1,4-cyclohexanedione + NADPH + H+ + O2
?
-
92% of the activity with (1R,4R)-dihydrocarvone
-
-
?
2,2-dimethylcyclohexanone + NADPH + H+ + O2
?
-
161% of the activity with (1R,4R)-dihydrocarvone
-
-
?
2,6-dimethylcyclohexanone + NADPH + H+ + O2
?
-
108% of the activity with (1R,4R)-dihydrocarvone
-
-
?
2-allylcyclohexanone + NADPH + H+ + O2
?
-
145% of the activity with (1R,4R)-dihydrocarvone
-
-
?
2-chlorocyclohexanone + NADPH + H+ + O2
?
-
112% of the activity with (1R,4R)-dihydrocarvone
-
-
?
2-methoxycyclohexanone + NADPH + H+ + O2
?
-
168% of the activity with (1R,4R)-dihydrocarvone
-
-
?
2-methylcyclohexanone + NADPH + H+ + O2
?
-
155% of the activity with (1R,4R)-dihydrocarvone
-
-
?
2-phenylcyclohexanone + NADPH + O2
?
-
148% of the activity with (1R,4R)-dihydrocarvone
-
-
?
3-methylcyclohexanone + NADPH + H+ + O2
?
-
151% of the activity with (1R,4R)-dihydrocarvone
-
-
?
4-methylcyclohexanone + NADPH + H+ + O2
?
-
40% of the activity with (1R,4R)-dihydrocarvone
-
-
?
8-mercaptomenthone + NADPH + H+ + O2
?
-
14% of the activity with (1R,4R)-dihydrocarvone
-
-
?
cycloheptanone + NADPH + H+ + O2
?
-
10% of the activity with (1R,4R)-dihydrocarvone
-
-
?
cyclohexanone + NADPH + H+ + O2
?
-
151% of the activity with (1R,4R)-dihydrocarvone
-
-
?
cyclopentanone + NADPH + H+ + O2
?
-
12% of the activity with (1R,4R)-dihydrocarvone
-
-
?
dihydrocarvone + NADPH + O2
4-isopropenyl-7-methyl-2-oxo-oxepanone + NADP+ + H2O
-
no activity with NADH
-
-
?
norcamphor + NADPH + H+ + O2
?
-
145% of the activity with (1R,4R)-dihydrocarvone
-
-
?
additional information
?
-
(1R)-pulegone + NADPH + H+ + O2
?
-
31% of the activity with (1R,4R)-dihydrocarvone
-
-
?
(1R)-pulegone + NADPH + H+ + O2
?
-
31% of the activity with (1R,4R)-dihydrocarvone
-
-
?
(1R,4R)-dihydrocarvone + NADPH + H+ + O2
(4R,7R)-4-isopropenyl-7-methyl-2-oxo-oxepanone + NADP+ + H2O
-
-
-
-
?
(1R,4R)-dihydrocarvone + NADPH + H+ + O2
(4R,7R)-4-isopropenyl-7-methyl-2-oxo-oxepanone + NADP+ + H2O
-
-
-
-
?
(1R,4S)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2
(3S)-3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
-
-
-
-
?
(1R,4S)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2
(3S)-3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
-
-
-
-
?
(1R,4S)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2
3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
-
3-isopropenyl-6-oxoheptanoate is the spontaneous rearrangement product of the lactone formed by MMKMO. 133% of the activity with (1R,4R)-dihydrocarvone
-
-
?
(1R,4S)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2
3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
-
3-isopropenyl-6-oxoheptanoate is the spontaneous rearrangement product of the lactone formed by MMKMO. 133% of the activity with (1R,4R)-dihydrocarvone
-
-
?
additional information
?
-
-
MMKMO is involved in the conversion of the monocyclic monoterpene ketone intermediates formed in the degradation pathways of all stereoisomers of three different monocyclic monoterpenes, i.e. limonene, (dihydro)carveol and menthol. MMKMO converts all enantiomers of the natural substrates with almost equal efficiency
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-
?
additional information
?
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NADPH-dependent 1-hydroxy-2-oxolimonene 1,2-monooxygenase is involved in the limonene degradation pathway
-
-
?
additional information
?
-
-
MMKMO converts all enantiomers of the natural substrates with almost equal efficiency. No activity with NADH
-
-
?
additional information
?
-
-
NADPH-dependent 1-hydroxy-2-oxolimonene 1,2-monooxygenase is involved in the limonene degradation pathway
-
-
?
additional information
?
-
-
MMKMO is involved in the conversion of the monocyclic monoterpene ketone intermediates formed in the degradation pathways of all stereoisomers of three different monocyclic monoterpenes, i.e. limonene, (dihydro)carveol and menthol. MMKMO converts all enantiomers of the natural substrates with almost equal efficiency
-
-
?
additional information
?
-
-
MMKMO converts all enantiomers of the natural substrates with almost equal efficiency. No activity with NADH
-
-
?
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1.14.13.105 monocyclic monoterpene ketone monooxygenase
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