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Information on EC 1.13.11.72 - 2-hydroxyethylphosphonate dioxygenase

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IUBMB Comments
Requires non-heme-Fe(II). Isolated from some bacteria including Streptomyces hygroscopicus and Streptomyces viridochromogenes. The pro-R hydrogen at C-2 of the ethyl group is retained by the formate ion. Any stereochemistry at C-1 of the ethyl group is lost. One atom from dioxygen is present in each product. Involved in phosphinothricin biosynthesis.
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The expected taxonomic range for this enzyme is: Streptomyces viridochromogenes
Synonyms
HEPD, PhdP, phpD, more
REACTION
REACTION DIAGRAM
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ORGANISM
UNIPROT
LITERATURE
2-hydroxyethylphosphonate + O2 = hydroxymethylphosphonate + formate
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