Organism | UniProt | Comment | Textmining |
---|---|---|---|
Streptomyces viridochromogenes | Q5IW40 | - |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(R)-2-hydroxyethylphosphonate + O2 | - |
Streptomyces viridochromogenes | hydroxymethylphosphonate + formate | product is almost racemic | ? | |
(S)-2-hydroxyethylphosphonate + O2 | - |
Streptomyces viridochromogenes | hydroxymethylphosphonate + formate | product is almost racemic | ? | |
2-hydroxyethylphosphonate + O2 | mechanism involves removal of the pro-S hydrogen at C2 and the loss of stereochemical information at C1. Thus, the hydroperoxylation mechanism, previously proposed as the product of a Criegee rearrangement, cannot be operational for conversion of 2-hydroxyethylphosphonate | Streptomyces viridochromogenes | hydroxymethylphosphonate + formate | - |
? |