EC Explorer
[browse EC tree] - [search]
EC 1.14.11.43 Details
show Brenda entryEC number
1.14.11.43
Accepted name
(S)-dichlorprop dioxygenase (2-oxoglutarate)
Reaction
(1) (S)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2 = 4-chloro-2-methylphenol + pyruvate + succinate + CO2;;
(2) (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 = 2,4-dichlorophenol + pyruvate + succinate + CO2
Other name(s)
SdpA,
α-ketoglutarate-dependent (S)-dichlorprop dioxygenase,
(S)-phenoxypropionate/α-ketoglutarate-dioxygenase,
2-oxoglutarate-dependent (S)-dichlorprop dioxygenase,
(S)-mecoprop dioxygenase,
2-oxoglutarate-dependent (S)-mecoprop dioxygenase
Systematic name
(S)-2-(4-chloro-2-methylphenoxy)propanoate,2-oxoglutarate:oxygen oxidoreductase (pyruvate-forming)
Comment
Fe2+-dependent enzyme. The enzymes from the Gram-negative bacteria Delftia acidovorans MC1 and Sphingomonas herbicidovorans MH are involved in the degradation of the (S)-enantiomer of the phenoxyalkanoic acid herbicides mecoprop and dichlorprop [1,2].
History
created 2013
back to topEC Tree
1 Oxidoreductases
1.1 Acting on the CH-OH group of donors
1.6.4.1 created 1961, deleted 2002 1.6.4.2 created 1961, modified 1989, deleted 2002 1.6.4.3 created 1961, modified 1976, deleted 1983 1.6.4.4 created 1965, deleted 2002 1.6.4.5 created 1972, deleted 2002 1.6.4.6 created 1972, deleted 2002 1.6.4.7 created 1978, deleted 2002 1.6.4.8 created 1989, deleted 2002 1.6.4.9 created 1992, deleted 2002 1.6.4.10 created 1992, deleted 2002 1.14.11.5 created 1972, deleted 1976
