1.1.1.421: D-apionate oxidoisomerase

This is an abbreviated version!
For detailed information about D-apionate oxidoisomerase, go to the full flat file.

Reaction

Synonyms

apnO

ECTree

     1 Oxidoreductases

         1.1 Acting on the CH-OH group of donors

             1.1.1 With NAD⁺ or NADP⁺ as acceptor

                1.1.1.421 D-apionate oxidoisomerase

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Systematic Name

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Systematic Name on EC 1.1.1.421 - D-apionate oxidoisomerase

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SYSTEMATIC NAME

IUBMB Comments

D-apionate:NAD+ oxidoreductase (isomerizing)

The enzyme, characterized from several bacterial species, participates in the degradation of D-apionate. The reaction involves migration of a hydroxymethyl group from position 3 to position 2 and oxidation of the 3-hydroxyl group. Stereospecificity of the product, 3-oxoisoapionate, has not been determined.