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Information on EC 1.3.1.122 - (S)-8-oxocitronellyl enol synthase

for references in articles please use BRENDA:EC1.3.1.122
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IUBMB Comments
Isolated from the plants Catharanthus roseus, Olea europaea (common olive), and several Nepeta species. The enzyme reduces 8-oxogeranial, generating an unstable product that is subsequently cyclized into several possible products, either non-enzymically or by dedicated cyclases. The products, known as iridoids, are involved in the biosynthesis of many indole alkaloids. cf. EC 1.3.1.123, 7-epi-iridoid synthase.
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The enzyme appears in viruses and cellular organisms
Synonyms
CrIS, CrISY, CrP5betaR4, CrP5betaR5, iridoid cyclase, iridoid synthase, IRIS, ISY, OeISY, P5betaR5, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(S)-8-oxocitronellyl enol + NAD(P)+ = (6E)-8-oxogeranial + NAD(P)H + H+
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