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menth-8-en-2-ol:NAD+ oxidoreductase
This enzyme from the Gram-positive bacterium Rhodococcus erythropolis DCL14 forms part of the carveol and dihydrocarveol degradation pathway. The enzyme accepts all eight stereoisomers of menth-8-en-2-ol as substrate, although some isomers are converted faster than others. The preferred substrates are (+)-neoisodihydrocarveol, (+)-isodihydrocarveol, (+)-dihydrocarveol and (-)-isodihydrocarveol.
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(1R,2R,4R)-dihydrocarveol + NAD+
(1R,4R)-dihydrocarvone + NADH + H+
(1R,2S,4R)-neo-dihydrocarveol + NAD+
(1R,4R)-dihydrocarvone + NADH + H+
(1S,2R,4R)-neoisodihydrocarveol + NAD+
(1S,4R)-iso-dihydrocarvone + NADH + H+
(1S,2S,4R)-iso-dihydrocarveol + NAD+
(1S,4R)-iso-dihydrocarvone + NADH + H+
(1R,2R,4R)-dihydrocarveol + NAD+
(1R,4R)-dihydrocarvone + NADH + H+
-
Substrates: -
Products: -
?
(1R,2R,4R)-dihydrocarveol + NAD+
(1R,4R)-dihydrocarvone + NADH + H+
-
Substrates: -
Products: -
?
(1R,2S,4R)-neo-dihydrocarveol + NAD+
(1R,4R)-dihydrocarvone + NADH + H+
-
Substrates: -
Products: -
?
(1R,2S,4R)-neo-dihydrocarveol + NAD+
(1R,4R)-dihydrocarvone + NADH + H+
-
Substrates: -
Products: -
?
(1S,2R,4R)-neoisodihydrocarveol + NAD+
(1S,4R)-iso-dihydrocarvone + NADH + H+
-
Substrates: -
Products: -
?
(1S,2R,4R)-neoisodihydrocarveol + NAD+
(1S,4R)-iso-dihydrocarvone + NADH + H+
-
Substrates: -
Products: -
?
(1S,2S,4R)-iso-dihydrocarveol + NAD+
(1S,4R)-iso-dihydrocarvone + NADH + H+
-
Substrates: -
Products: -
?
(1S,2S,4R)-iso-dihydrocarveol + NAD+
(1S,4R)-iso-dihydrocarvone + NADH + H+
-
Substrates: -
Products: -
?
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