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EC 1.14.20.7 Details
EC number
1.14.20.7
Accepted name
2-oxoglutarate/L-arginine monooxygenase/decarboxylase (succinate-forming)
Reaction
L-arginine + 2-oxoglutarate + O2 = succinate + CO2 + guanidine + (S)-1-pyrroline-5-carboxylate + H2O (overall reaction);;(1a) L-arginine + 2-oxoglutarate + O2 = succinate + CO2 + 5-hydroxy-L-arginine;;(1b) 5-hydroxy-L-arginine = guanidine + (S)-1-pyrroline-5-carboxylate + H2O
Other name(s)
ethene-forming enzyme, ethylene-forming enzyme, EFE
Systematic name
L-arginine,2-oxoglutarate:oxygen oxidoreductase (succinate-forming)
Comment
This is one of two simultaneous reactions catalysed by the enzyme, which is responsible for ethylene production in bacteria of the Pseudomonas syringae group. In the other reaction [EC 1.13.12.19, 2-oxoglutarate dioxygenase (ethene-forming)] the enzyme catalyses the dioxygenation of 2-oxoglutarate forming ethene and three molecules of carbon dioxide.The enzyme catalyses two cycles of the ethene-forming reaction for each cycle of the succinate-forming reaction, so that the stoichiometry of the products ethene and succinate is 2:1.
History
created 2011 as EC 1.14.11.34, transferred 2018 to EC 1.14.20.7
EC Tree
1.6.7.1 created 1972, deleted 1978
1.6.7.2 created 1972, deleted 1978
1.6.7.3 created 1978, deleted 1978
1.6.8.1 created 1981, deleted 2002
1.6.8.2 created 1982, deleted 2002