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EC 1.14.13.119 Details
EC number
1.14.13.119
Accepted name
5-epiaristolochene 1,3-dihydroxylase
Reaction
5-epiaristolochene + 2 NADPH + 2 H+ + 2 O2 = capsidiol + 2 NADP+ + 2 H2O
Other name(s)
5-epi-aristolochene 1,3-dihydroxylase,
EAH
Systematic name
5-epiaristolochene,NADPH:oxygen oxidoreductase (1- and 3-hydroxylating)
Comment
A heme-thiolate protein (P-450). Kinetic studies suggest that 1β-hydroxyepiaristolochene is mainly formed first followed by hydroxylation at C-3. However the reverse order via 3α-hydroxyepiaristolochene does occur.
History
created 2011, deleted 2018
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