1.14.13.69: alkene monooxygenase

This is an abbreviated version!
For detailed information about alkene monooxygenase, go to the full flat file.

Word Map on EC 1.14.13.69

Reaction

Propene
+
NADH
+
H+
+
O2
=
1,2-Epoxypropane
+
NAD+
+
H2O

Synonyms

AkMO, alkene epoxygenase, alkene monooxygenase, AMO, EtnC, More, propene monooxygenase, XAMO

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.13.69 alkene monooxygenase

Cofactor

Cofactor on EC 1.14.13.69 - alkene monooxygenase

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COFACTOR
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
additional information
the enzyme contains a Rieske-type ferredoxin. AMO requires a small catalytic coupling/effector protein, AamD, the coupling protein cannot or very poorly be substituted by coupling proteins of AMOs of other species, e.g. IsoD from Rhodococcus sp. strain AD45, or PmoB from Mycobacterium sp. strain M156, substitution with IsoD changes the regioselectivity of toluene hydroxylation and stereoselectivity of styrene epoxidation, although this is accompanied by a high level of uncoupling, overview
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