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1.13.11.85: exo-cleaving rubber dioxygenase

This is an abbreviated version!
For detailed information about exo-cleaving rubber dioxygenase, go to the full flat file.

Word Map on EC 1.13.11.85

Reaction

cis-1,4-polyisoprene
+ n O2 = n (4Z,8Z)-4,8-dimethyl-12-oxotrideca-4,8-dienal

Synonyms

heme-dependent rubber oxygenase, LATA, poly(cis-1,4-isoprene)-cleavage enzyme, roxA, RoxB, RubA, rubber oxygenase, rubber oxygenase A

ECTree

     1 Oxidoreductases
         1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)
             1.13.11 With incorporation of two atoms of oxygen
                1.13.11.85 exo-cleaving rubber dioxygenase

Natural Substrates Products

Natural Substrates Products on EC 1.13.11.85 - exo-cleaving rubber dioxygenase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
cis-1,4-polyisoprene + n O2
?
show the reaction diagram
cis-1,4-polyisoprene + n O2
n (4Z,8Z)-4,8-dimethyl-12-oxotrideca-4,8-dienal
show the reaction diagram
cis-1,4-polyisoprene + O2
(4Z,8Z)-4,8-dimethyl-12-oxotrideca-4,8-dienal
show the reaction diagram
rubber latex + O2
(4Z,8Z)-4,8-dimethyl-12-oxotrideca-4,8-dienal
show the reaction diagram
the enzyme is excreted by Xanthomonas to functionalize and cleave the inert latex biopolymer poly(cis-1,4-isoprene) into the more soluble (4Z,8Z)-4,8-dimethyl-12-oxotrideca-4,8-dienal units
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