1.3.1.108: caffeoyl-CoA reductase
This is an abbreviated version!
For detailed information about caffeoyl-CoA reductase, go to the full flat file.
Word Map on EC 1.3.1.108
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1.3.1.108
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abasic
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anteroposterior
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apurinic
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site-containing
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2-amino-4-phosphonobutyrate
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apyrimidinic
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masker
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acetabular
- 1.3.1.108
-
abasic
-
anteroposterior
-
apurinic
-
site-containing
- 2-amino-4-phosphonobutyrate
-
apyrimidinic
-
masker
-
acetabular
Reaction
+ 2 NAD+ + 2 reduced ferredoxin [iron-sulfur] cluster = + 2 NADH + 2 oxidized ferredoxin [iron-sulfur] cluster
Synonyms
caffeoyl-CoA reductase-Etf complex, electron-bifurcating caffeoyl-CoA reductase, hydrocaffeoyl-CoA:NAD+, ferredoxin oxidoreductase
ECTree
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Systematic Name
Systematic Name on EC 1.3.1.108 - caffeoyl-CoA reductase
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3-(3,4-dihydroxyphenyl)propanoyl-CoA:NAD+, ferredoxin oxidoreductase
The enzyme, characterized from the bacterium Acetobacterium woodii, contains two [4Fe-4S] clusters and FAD. The enzyme couples the endergonic ferredoxin reduction with NADH as reductant to the exergonic reduction of caffeoyl-CoA with the same reductant. It uses the mechanism of electron bifurcation to overcome the steep energy barrier in ferredoxin reduction. It also reduces 4-coumaroyl-CoA and feruloyl-CoA.