EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Coprinopsis cinerea |
delta-cadinene + diphosphate |
major product |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Helianthus annuus |
delta-cadinene + diphosphate |
delta-cadinene is one of the two main products, while alpha-muuorlene, beta-caryophyllene, alpha-humulene and alpha-copaene are minor products |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Phyla dulcis |
delta-cadinene + diphosphate |
bifunctional sesquiterpene synthase producing both alpha-copaene and delta-cadinene |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Coprinopsis cinerea ATCC MYA-4618 |
delta-cadinene + diphosphate |
major product |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Gossypium hirsutum |
(+)-delta-cadinene + diphosphate |
- |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Gossypium arboreum |
(+)-delta-cadinene + diphosphate |
- |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Piper nigrum |
(+)-delta-cadinene + diphosphate |
- |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Ricinus communis |
(+)-delta-cadinene + diphosphate |
products are about 60% (-)-alpha-copaene, 40% (+)-delta-cadinene |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate |
- |
Gossypium arboreum |
(+)-delta-cadinene + germacradien-4-ol + diphosphate |
- |
? |
4.2.3.13 | (2E,6E)-farnesyl diphosphate + H2O |
Cop4 generates a tertiary cadinyl cation which upon deprotonation yields its major cyclization product delta-cadinene. The cadinyl cation reacts further to yield other cyclization products (beta-cubebene, cubebol , beta-copaene, sativene) |
Coprinopsis cinerea |
delta-cadinene + diphosphate |
- |
? |