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Results 1 - 10 of 88 > >>
EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(-)-limonene oxide + H2O - uncultured organism (1R,2R,4S)-limonene-1,2-diol - ?
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S)-1-methylcyclohexane oxide + H2O - Rhodococcus erythropolis (1S,2S)-1-methylcyclohexane-1,2-diol - ir
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S,4R)-limonene-1,2-epoxide + H2O - Rhodococcus erythropolis (1S,2S,4R)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S,4R)-limonene-1,2-epoxide + H2O the reaction mechanism involves epoxide protonation by Asp109, nucleophilic attack by water, and abstraction of a proton from water by Asp132. The isopropenyl group plays a crucial role because it restricts the half-chair conformation to one of the two possible helicities. In this conformation, attack on the different epoxide carbons will lead to either a chair-like or a twist-boat transition state structure, the latter resulting in a higher barrier. The regioselectivity is thus governed by conformational and not electronic factors Rhodococcus erythropolis (1S,2S,4R)-limonene-1,2-diol - ir
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S,4R)-limonene-1,2-epoxide + H2O the reaction mechanism involves epoxide protonation by Asp109, nucleophilic attack by water, and abstraction of a proton from water by Asp132. The isopropenyl group plays a crucial role because it restricts the half-chair conformation to one of the two possible helicities. In this conformation, attack on the different epoxide carbons will lead to either a chair-like or a twist-boat transition state structure, the latter resulting in a higher barrier. The regioselectivity is thus governed by conformational and not electronic factors Rhodococcus erythropolis DCL14 (1S,2S,4R)-limonene-1,2-diol - ir
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S,4R)-limonene-1,2-epoxide + H2O - Rhodococcus erythropolis (1R,2S,4R)-limonene-1,2-diol - ?
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S,4R)-limonene-1,2-epoxide + H2O - uncultured organism (1R,2S,4R)-limonene-1,2-diol - ?
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S,4S)-limonene-1,2-epoxide + H2O - Rhodococcus erythropolis (1R,2R,4S)-limonene-1,2-diol optically pure, diastereomeric excess above 99% ?
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S,4S)-limonene-1,2-epoxide + H2O the reaction mechanism involves epoxide protonation by Asp109, nucleophilic attack by water, and abstraction of a proton from water by Asp132. The isopropenyl group plays a crucial role because it restricts the half-chair conformation to one of the two possible helicities. In this conformation, attack on the different epoxide carbons will lead to either a chair-like or a twist-boat transition state structure, the latter resulting in a higher barrier. The regioselectivity is thus governed by conformational and not electronic factors Rhodococcus erythropolis (1R,2R,4S)-limonene-1,2-diol - ir
Display the word mapDisplay the reaction diagram Show all sequences 3.3.2.8(1R,2S,4S)-limonene-1,2-epoxide + H2O the reaction mechanism involves epoxide protonation by Asp109, nucleophilic attack by water, and abstraction of a proton from water by Asp132. The isopropenyl group plays a crucial role because it restricts the half-chair conformation to one of the two possible helicities. In this conformation, attack on the different epoxide carbons will lead to either a chair-like or a twist-boat transition state structure, the latter resulting in a higher barrier. The regioselectivity is thus governed by conformational and not electronic factors Rhodococcus erythropolis DCL14 (1R,2R,4S)-limonene-1,2-diol - ir
Results 1 - 10 of 88 > >>