EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.14.45 | (E)-4-hydroxyphenylacetaldoxime + O2 + [reduced NADPH-hemoprotein reductase] |
- |
Arabidopsis thaliana |
1-aci-nitro-2-(4-hydroxyphenyl)-ethane + H2O + [oxidized NADPH-hemoprotein reductase] |
- |
? |
1.14.14.45 | (E)-indol-3-ylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 |
- |
Arabidopsis thaliana |
S-[(E)-N-hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
overall reaction |
? |
1.14.14.45 | (E)-p-hydroxyphenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 |
- |
Arabidopsis thaliana |
S-[(Z)-N-hydroxy(p-hydroxyphenyl)acetimidoyl]-L-glutathione + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
overall reaction |
? |
1.14.14.45 | (E)-p-hydroxyphenylacetaldoxime + NADPH + H+ + 2-mercaptoethanol |
- |
Arabidopsis thaliana |
(Z)-2-hydroxyethyl N,4-dihydroxybenzene-1-carboximidothioate + NADP+ + H2O |
CYP83B1 shows absolute specificity towards (E)-p-hydroxyphenylacetaldoxime as a substrate, and the (Z)-S-alkyl-thiohydroximate formed maintains the structural configuration of the oxime function as in the (E)-p-hydroxyphenylacetaldoxime substrate |
? |
1.14.14.45 | (E)-phenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 |
- |
Arabidopsis thaliana |
S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + [oxidized NADPH-hemoprotein reductase] + 2 H2O |
overall reaction |
? |
1.14.14.45 | (E)-phenylacetaldoxime + O2 + [reduced NADPH-hemoprotein reductase] |
- |
Arabidopsis thaliana |
1-aci-nitro-2-phenylethane + H2O + [oxidized NADPH-hemoprotein reductase] |
- |
? |
1.14.14.45 | 1-aci-nitro-2-(4-hydroxyphenyl)-ethane + 2-mercaptoethanol |
- |
Arabidopsis thaliana |
(Z)-2-hydroxyethyl N-hydroxy-2-(4-hydroxyphenyl)ethanimidothioate + H2O |
- |
? |
1.14.14.45 | an (E)-omega-(methylthio)alkanal oxime + O2 + glutathione + [reduced NADPH-hemoprotein reductase] |
- |
Arabidopsis thaliana |
an (E)-1-(glutathione-S-yl)-omega-(methylthio)alkylhydroximate + 2 H2O + [oxidized NADPH-hemoprotein reductase] |
- |
? |
1.14.14.45 | indole-3-acetaldoxime + O2 + glutathione + [reduced NADPH-hemoprotein reductase] |
- |
Arabidopsis thaliana |
1-aci-nitro-2-indolyl-ethane + H2O + [oxidized NADPH-hemoprotein reductase] |
- |
? |
1.14.14.45 | indole-3-acetaldoxime + O2 + glutathione + [reduced NADPH-hemoprotein reductase] |
indole-3-acetaldoxime is the physiological substrate for CYP83B1 |
Arabidopsis thaliana |
1-aci-nitro-2-indolyl-ethane + H2O + [oxidized NADPH-hemoprotein reductase] |
- |
? |