EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.14.40 | (E)-4-hydroxyphenylacetaldoxime + O2 + [reduced NADPH-hemoprotein reductase] |
- |
Sorghum bicolor |
1-aci-nitro-2-(4-hydroxyphenyl)-ethane + H2O + [oxidized NADPH-hemoprotein reductase] |
first step of reaction |
? |
1.14.14.40 | 1-aci-nitro-2-(4-hydroxyphenyl)-ethane + 2-mercaptoethanol |
- |
Sorghum bicolor |
(Z)-2-hydroxyethyl N-hydroxy-2-(4-hydroxyphenyl)ethanimidothioate + H2O |
- |
? |
1.14.14.40 | an (E)-omega-(methylthio)alkanal oxime + O2 + glutathione + [reduced NADPH-hemoprotein reductase] |
- |
Sorghum bicolor |
an (E)-1-(glutathione-S-yl)-omega-(methylthio)alkylhydroximate + 2 H2O + [oxidized NADPH-hemoprotein reductase] |
overall reaction |
? |
1.14.14.40 | L-phenylalanine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase] |
- |
Arabidopsis thaliana |
(E)-phenylacetaldoxime + 2 [oxidized NADPH-hemoprotein reductase] + CO2 + 3 H2O |
overall reaction |
? |
1.14.14.40 | L-phenylalanine + 2 O2 + 2 [reduced NADPH-hemoprotein reductase] |
- |
Prunus mume |
(E)-phenylacetaldoxime + 2 [oxidized NADPH-hemoprotein reductase] + CO2 + 3 H2O |
overall reaction |
? |
1.14.14.40 | L-phenylalanine + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 |
- |
Arabidopsis thaliana |
(E)-phenylacetaldoxime + 2 [oxidized NADPH-hemoprotein reductase] + CO2 + 3 H2O |
- |
? |
1.14.14.40 | more |
neither L-tyrosine, L-tryptophan, L-methionine, nor DL-homophenylalanine are metabolized by CYP79A2 |
Arabidopsis thaliana |
? |
- |
? |
1.14.14.40 | more |
CYP83B1 catalyzes the conversion of the (E)-p-hydroxyphenylacetaldoxime into an S-alkyl-thiohydroximate with retention of the configuration of the E-oxime intermediate in the final glucosinolate core structure. CYP83B1 from Arabidopsis thaliana cannot convert the (E)-p-hydroxyphenylacetaldoxime to the (Z)-isomer, which blocks the route towards cyanogenic glucoside synthesis |
Sorghum bicolor |
? |
- |
? |
1.14.14.40 | more |
no substrates: L-tyrosine, L-tryptophan, L-methionine, or DL-homophenylalanine |
Arabidopsis thaliana |
? |
- |
? |
1.14.14.40 | more |
the enzyme is specific for L-phenylalanine. No substrates: L-Tyr, L-Trp, and L-Val |
Prunus mume |
? |
- |
? |