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Results 1 - 6 of 6
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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 1.14.13.216asperlicin C + FADH2 + O2 the instability of the product generated from the reaction of AspB with the enantiomer of asperlicin C (ent-asperlicin C) hinders full characterization, formation of an oxidized product, which is stalled prior to intramolecular cyclization en route to an asperlicin E type product Aspergillus alliaceus asperlicin E + FAD + H2O with NAD(P)H as reducing element, product determination by NMR spectroscopy ?
Display the reaction diagram Show all sequences 1.14.13.216asperlicin C + FADH2 + O2 with NAD(P)H as reducing element. AspB mediated transformation of asperlicin C to asperlicin E via formation of the transient indole epoxide or a hydroxyiminium adduct (via a FAD-4a-OOH electrophilic oxygen donation to the indole 2, 3-double bond), with presumed alpha stereochemistry Aspergillus alliaceus asperlicin E + FAD + H2O - ?
Display the reaction diagram Show all sequences 1.14.13.216asperlicin C + FADH2 + O2 the instability of the product generated from the reaction of AspB with the enantiomer of asperlicin C (ent-asperlicin C) hinders full characterization, formation of an oxidized product, which is stalled prior to intramolecular cyclization en route to an asperlicin E type product Aspergillus alliaceus ATCC 20656 asperlicin E + FAD + H2O with NAD(P)H as reducing element, product determination by NMR spectroscopy ?
Display the reaction diagram Show all sequences 1.14.13.216asperlicin C + FADH2 + O2 with NAD(P)H as reducing element. AspB mediated transformation of asperlicin C to asperlicin E via formation of the transient indole epoxide or a hydroxyiminium adduct (via a FAD-4a-OOH electrophilic oxygen donation to the indole 2, 3-double bond), with presumed alpha stereochemistry Aspergillus alliaceus ATCC 20656 asperlicin E + FAD + H2O - ?
Display the reaction diagram Show all sequences 1.14.13.216more the enzyme converts synthetic asperlicin C or D (and their enantiomers) in the presence of proposed cosubstrate O2 to new products. No activity with asperlicin D and fumiquinazoline F by enzyme AspB Aspergillus alliaceus ? - ?
Display the reaction diagram Show all sequences 1.14.13.216more the enzyme converts synthetic asperlicin C or D (and their enantiomers) in the presence of proposed cosubstrate O2 to new products. No activity with asperlicin D and fumiquinazoline F by enzyme AspB Aspergillus alliaceus ATCC 20656 ? - ?
Results 1 - 6 of 6
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