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Results 1 - 7 of 7
EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
4-nitro-6-oxohepta-2,4-dienedioate
-
2-oxo-3-(5-oxofuran-2-ylidene)propanoate + nitrite
2nd step of reaction, spontaneous
?
5-chlorosalicylate + O2
-
2-oxo-3-(5-oxofuran-2-ylidene)propanoate + chloride
overall reaction
?
5-nitrosalicylate + O2
oxidation catalyzed by cell extracts requires 0.97 mol O2/mol 5-nitrosalicylate
2-oxo-3-(5-oxofuran-2-ylidene)propanoate + nitrite
overall reaction
?
5-nitrosalicylate + O2
results are consistent with a dioxygenase-catalyzed ring opening followed by spontaneous lactonization and nitrite elimination and enzyme-catalyzed hydrolysis of the lactone to produce maleylpyruvate
2-oxo-3-(5-oxofuran-2-ylidene)propanoate + nitrite
overall reaction. The initial ring fission product of 5-nitrosalicylate dioxygenation is spontaneously and rapidly cyclized to form lactones, accompanied by the release of NO2-
?
5-nitrosalicylate + O2
-
4-nitro-6-oxohepta-2,4-dienedioate
1st step of reaction
?
more
no substrates: 4-chlorocatechol, 4-nitrocatechol
?
-
?
salicylate + O2
-
?
-
?
Results 1 - 7 of 7