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2.3.1.B39
physiological function
enzyme is involved in biosynthesis of brefeldin A. It synthesizes the precisely reduced oktaketide precursor, which can then be directly offloaded by the thiohydrolase enzyme followed by a P450-mediated formation of the cyclopentane ring and macrocyclization to afford 7-deoxy brefeldin A.thiolase Bref-TH controls the programmed release of the oktaketide product from synthase Bref-PKS
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