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EC Number General Information Commentary Reference
Display the reaction diagram Show all sequences 1.14.19.32evolution origin and evolution of the DELTA14 desaturase, phylogenetic analysis and tree, detailed overview 733577
Display the reaction diagram Show all sequences 1.14.19.32metabolism the enzyme is involved in biosynthesis of (Z)-12- and (E)-12-tetradecenyl acetates 698285
Display the reaction diagram Show all sequences 1.14.19.32metabolism the enzyme is involved in the sex pheromone biosynthetic pathway. Two pathways exist, both initiate from C16:acyl-CoA, with one involving DELTA14 and DELTA9 desaturation to generate Z9,E12-14:acyl, and the other involving the chain shortening of C16:acyl-CoA to C14:acyl-CoA, followed by DELTA12 and DELTA9 desaturation to generate Z9,E12-14:acyl-CoA. Then, a final reduction and acetylation generates Z9,E12-14:OAc, overview. Desaturases introduce a double bond into the fatty acyl carbon chain, with strict regio- and stereo-selectivity 733577
Display the reaction diagram Show all sequences 1.14.19.32physiological function the enzyme is involved in the synthesis of pheromone compound (Z,E)-9,12-tetradecadienyl acetate from pheromone precursor palmitoyl-CoA 733577
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