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1.11.1.B6
evolution
vanadium-dependent haloperoxidases (VPXOs) are a class of enzymes that catalyze selective oxidation reactions for which vanadium is an essential cofactor converting halides to form halogenated organic products and water. These enzymes include chloroperoxidase and bromoperoxidase, which have very different protein sequences and sizes, but regardless the coordination environment of the active sites is constant. Coordination chemistry of the vanadium(V) center in the different vanadium-haloperoxidases, overview
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765199
1.11.1.B6
more
structure of bound peroxidovanadium(V) in the active site of the vanadium-containing haloperoxidases, overview
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765199
1.11.1.B6
physiological function
vanadium-dependent bromoperoxidases catalyze reactions involving peroxides and bromide or iodide ions
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765199
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