EC Number   |
Reaction |
Reference |
|---|
    4.4.1.21 | S-(5-deoxy-D-ribos-5-yl)-L-homocysteine = L-homocysteine + (4S)-4,5-dihydroxypentan-2,3-dione |
- |
- |
| 4.4.1.21 | S-(5-deoxy-D-ribos-5-yl)-L-homocysteine = L-homocysteine + (4S)-4,5-dihydroxypentan-2,3-dione |
catalytic mechanism in which the metal ion catalyzes an intramolecular redox reaction, shifting the carbonyl group from the C-1 position to the C-3 position of the ribose. Subsequent beta-elimination at the C-4 and C-5 position releases homocysteine as a free thiol |
654703 |
| 4.4.1.21 | S-(5-deoxy-D-ribos-5-yl)-L-homocysteine = L-homocysteine + (4S)-4,5-dihydroxypentan-2,3-dione |
catalytic mechanism, the substrate may bind within the active site when its ribosyl moiety is in the alpha- or beta-furanose configuration or as a linear aldose, docking and molecular dynamics simulations |
730256 |
