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3.2.1.147
a thioglucoside + H2O = a sugar + a thiol
reaction mechanism
753337
3.2.1.147
a thioglucoside + H2O = a sugar + a thiol
the mechanism involves a first step acid-base catalyzed reaction with the formation of the glycosyl enzyme intermediate and the benzyl isothiocyanate obtained by the enzyme-independent Lossen rearrangement of the transient thiohydroximate-O-sulfonate, a sulfate anion and a proton are also released
208588
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