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Results 1 - 8 of 8
EC Number Reaction Commentary Reference
Show all pathways known for 2.5.1.19Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.19phosphoenolpyruvate + 3-phosphoshikimate = phosphate + 5-O-(1-carboxyvinyl)-3-phosphoshikimate - -
Show all pathways known for 2.5.1.19Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.19phosphoenolpyruvate + 3-phosphoshikimate = phosphate + 5-O-(1-carboxyvinyl)-3-phosphoshikimate binding of shikimate 3-phosphate leads to a saturable and stable conformational change in the isolated N-terminal domain 638206
Show all pathways known for 2.5.1.19Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.19phosphoenolpyruvate + 3-phosphoshikimate = phosphate + 5-O-(1-carboxyvinyl)-3-phosphoshikimate catalytic mechanism, tetrahedral reaction intermediate, active site structure, wild-type and mutant D313A 659285
Show all pathways known for 2.5.1.19Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.19phosphoenolpyruvate + 3-phosphoshikimate = phosphate + 5-O-(1-carboxyvinyl)-3-phosphoshikimate catalytic mechanism, tetrahedral reaction intermediate, catalytic cycle of the enzyme, overview 658112
Show all pathways known for 2.5.1.19Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.19phosphoenolpyruvate + 3-phosphoshikimate = phosphate + 5-O-(1-carboxyvinyl)-3-phosphoshikimate enolpyruvylshikimate 3-phosphate ketal is catalytically formed as side product upon enolpyruvyl activation through protonation by an intramolecular nucleophilic addition of O4 to C2’ of the enolpyruvyl moiety 678255
Show all pathways known for 2.5.1.19Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.19phosphoenolpyruvate + 3-phosphoshikimate = phosphate + 5-O-(1-carboxyvinyl)-3-phosphoshikimate ordered substrate binding with 3-phosphoshikimate being bound first 691936
Show all pathways known for 2.5.1.19Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.19phosphoenolpyruvate + 3-phosphoshikimate = phosphate + 5-O-(1-carboxyvinyl)-3-phosphoshikimate proposed mechanism 638176, 638177, 638201
Show all pathways known for 2.5.1.19Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.19phosphoenolpyruvate + 3-phosphoshikimate = phosphate + 5-O-(1-carboxyvinyl)-3-phosphoshikimate via formation of a tetrahedral intermediate (TI) after which residue His385 is in a neutral form while residues Lys22, Lys340 and Lys411 are protonated, Asp313 mediates attack of the TI C4-OH group (as oxyanion, shikimate-3-phosphate moiety) at the TI C3-methyl group (phosphoenolpyruvate moiety), Lys22 serves as general acid catalyst for TI breakdown 691197
Results 1 - 8 of 8