1.3.1.28 | (2S,3S)-2,3-dihydro-2,3-dihydroxybenzoate + NAD+ = 2,3-dihydroxybenzoate + NADH + H+ |
enzyme functions as an alcohol dehydrogenase which oxidizes the C3-hydroxylgroup of the substrate, the transient intermediate 2-hydroxy-3-oxo-4,6-cyclohexadiene-1-carboxylate undergoes rapid aromatization to give 2,3-dihydroxybenzoate |
390631 |