EC Number   |
Reaction |
Reference |
|---|
   1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
catalyzes the oxidation of methane through the activation of O2 at a nonheme biferrous center in the hydroxylase component MMOH |
685272 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
distribution of electrons in intermolecular electron-transfer intermediates, isomerization of the initial ternary complex is required for maximal electron-transfer rates |
-, 674158 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
kinetic model of protein component interaction |
438933 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
mechanism |
-, 438923, 438932, 438934, 438937 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
modeling of interaction between the different protein components of sMMO |
-, 438943 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
reaction cycle, via formation of the hydroperoxo intermediate compound P and the key reaction cycle intermediate compound Q, overview |
672102 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
reaction mechanism and reaction cycle of enzyme sMMO, via O2 activation intermediates, detailed overview |
-, 745389 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
reaction mechanism and regulation, catalytic cycle of sMMO, the enzyme complex causes quantum tunneling to dominate in CĀH bond cleavage reaction for methane, selectively increasing the rate for this substrate, mechanism of C-H bond cleavage, overview |
675455 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
reaction mechanism of enzyme sMMO. During methane oxidation, first, the regulatory protein docks at the alpha2beta2 interface of alpha2beta2gamma2 of hydroxylase and therefore triggering a conformational change in the alpha-subunit. Subsequently, the hydroxylase acts as a proton carrier allowing oxygen and methane interface with the di-iron center, overview |
-, 746420 |
| 1.14.13.25 | methane + NAD(P)H + H+ + O2 = methanol + NAD(P)+ + H2O |
reaction mechanism via carboxylate-bridged diiron center and dioxygen, a di(my-oxo)diiron(IV) intermediate termed Q is responsible for the catalytic activity with hydrocarbons, the peroxodiiron(III) intermediate precedes Q formation in the catalytic cycle, which consists of four principal steps, overview |
-, 674145 |
