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EC Number	Reaction	Commentary	Reference
1.13.11.46	4-hydroxyphenylpyruvate + O2 = (S)-4-hydroxymandelate + CO2	HMS uses Fe(IV)=O to perform hydroxylation of the benzylic carbon, reaction mechanism with electrophilic attack on the aromatic ring, and HMS catalytic cycle, overview	724365
1.13.11.46	4-hydroxyphenylpyruvate + O2 = (S)-4-hydroxymandelate + CO2	one oxygen from molecular oxygen is incorporated into the carboxyl group and one into the benzylic hydroxyl group	285255
1.13.11.46	4-hydroxyphenylpyruvate + O2 = (S)-4-hydroxymandelate + CO2	reaction mechanism, overview	724325, 724392

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Release 2023.1 (January 2023)