EC Number |
Reaction |
Reference |
---|
1.11.1.14 | 1-(3,4-dimethoxyphenyl)-2-(2-methoxyphenoxy)propane-1,3-diol + H2O2 = 3,4-dimethoxybenzaldehyde + 2-methoxyphenol + glycolaldehyde + H2O |
(1) |
- |
1.11.1.14 | 2 (3,4-dimethoxyphenyl)methanol + H2O2 = 2 (3,4-dimethoxyphenyl)methanol radical + 2 H2O |
(2) |
- |
1.11.1.14 | 2 (3,4-dimethoxyphenyl)methanol + H2O2 = 2 (3,4-dimethoxyphenyl)methanol radical + 2 H2O |
catalytic mechanism of LiP on the oxidation of phenolic substrates (AH) and LiP is protected from suicidal inactivation by veratryl alcohol cation radicals |
764607 |
1.11.1.14 | 2 (3,4-dimethoxyphenyl)methanol + H2O2 = 2 (3,4-dimethoxyphenyl)methanol radical + 2 H2O |
mechanism |
-, 394594, 394596, 394597, 394601, 394604 |
1.11.1.14 | 2 (3,4-dimethoxyphenyl)methanol + H2O2 = 2 (3,4-dimethoxyphenyl)methanol radical + 2 H2O |
proposed routes to bond-cleavage through a pre-protonation mechanism and an oxidation route and their respective protonated intermediates, reaction mechanism and pH-dependence, overview |
764353 |