1.11.1.10 | RH + chloride + H2O2 = RCl + 2 H2O |
substrate specificity and reaction mechanism, overview. Relative favorability of catalytic epoxidation and allylic hydroxylation of olefins, a type of alkene oxidation selectivity. The selectivity for epoxidation versus can be rationalized in terms of the proximal pocket's modulation of the thiolate's electron push and consequent influence on the heme redox potential and the basicity of the trans ligand |
765267 |