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EC Number Reaction Commentary Reference
Show all pathways known for 1.1.1.378Display the reaction diagram Show all sequences 1.1.1.378L-rhamnose + NAD(P)+ = L-rhamnono-1,4-lactone + NAD(P)H + H+ - -
Show all pathways known for 1.1.1.378Display the reaction diagram Show all sequences 1.1.1.378L-rhamnose + NAD(P)+ = L-rhamnono-1,4-lactone + NAD(P)H + H+ in putative catalytic mechanism, the C1-OH group of L-rhamnose is deprotonated by Tyr159 as a general basic catalyst, with concurrent transfer of the hydride ion to NAD(P)+, and the pKa value of its hydroxyl group is lowered by Lysl63, leading to the stabilization of the tyrosinate anion at physiological pH 763033
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