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Results 1 - 6 of 6
EC Number
Reaction
Commentary
Reference
D-Mannose 6-phosphate = D-fructose 6-phosphate
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D-Mannose 6-phosphate = D-fructose 6-phosphate
analysis of enzyme-substrate and enzyme-inhibitor complexes by ESI-FTICR mass spectrometry
D-Mannose 6-phosphate = D-fructose 6-phosphate
cis-enediol mechanism
D-Mannose 6-phosphate = D-fructose 6-phosphate
hydride transfer mechanism of a alpha-hydrogen bond between the C1 and C2 positions of substrate. Mechanism involves Zn2+ mediating the movement of a proton between O1 and O2, and the hydrophobic environment formed in part by T278 promoting transfer of a hydride ion
D-Mannose 6-phosphate = D-fructose 6-phosphate
mechanism does not involve trans-enediol. Instead, activity may result from additional space in the active site which permits rotation of the C2-C3 bond
D-Mannose 6-phosphate = D-fructose 6-phosphate
reaction mechanism, overview. Zn2+ binding induces structural order in the loop consisting of residues 50-54. The metal atom appears to play a role in substrate binding and is probably also important for maintaining the architecture of the active site. Isomerization probably follows a cis-enediol mechanism, overall folding pattern of the central catalytic domain, overview
Results 1 - 6 of 6