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EC Number Application Commentary Reference
Show all pathways known for 2.3.1.239Display the word mapDisplay the reaction diagram Show all sequences 2.3.1.239synthesis substrate engineering approaches to control the catalytic cycle of a full polykeitde synthase module harboring multiple domains. Using alternatively activated native hexaketide substrates, product formation may be controled with greater than 10:1 selectivity for either full module catalysis, leading to a 14-membered macrolactone, or direct cyclization to a 12-membered ring -, 736315
Show all pathways known for 2.3.1.239Display the word mapDisplay the reaction diagram Show all sequences 2.3.1.239synthesis versatile method for generating and identifying functional chimeric PKS enzymes for synthesizing custom macrolactones and macrolides. PKS genes from the pikromycin and erythromycin pathways are hybridized in Saccharomyces cerevisiae to generate hybrid libraries. Streptomyces venezuelae strains that expressed active chimeric enzymes with new functionality are capable of producing engineered macrolactones -, 736312
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