2.7.8.23	carboxyphosphonoenolpyruvate	first natural phosphinate	Streptomyces hygroscopicus SF1293	(hydroxyphosphinyl)pyruvate + CO2	-	?	358713	
2.7.8.23	carboxyphosphonoenolpyruvate	biosynthetic pathway that leads to the tripeptide antibiotic bialaphos, formation of one of the two C-P bonds in bialaphos	Streptomyces hygroscopicus SF1293	(hydroxyphosphinyl)pyruvate + CO2	-	?	358713	
2.7.8.23	carboxyphosphonoenolpyruvate	catalyzes the rearrangement of the carboxyphosphonogroup to form the C-P bond of phosphinopyruvate	Streptomyces hygroscopicus SF1293	(hydroxyphosphinyl)pyruvate + CO2	-	?	358713