1.14.13.160	(+-)-cis-bicyclo[3.2.0]hept-2-en-6-one + O2 + NADPH + H+	-	Pseudomonas putida	? + NADP+ + H2O	-	?	418134	
1.14.13.160	(+-)-cis-bicyclo[3.2.0]hept-2-en-6-one + O2 + NADPH + H+	-	Pseudomonas putida NCIMB 10007	? + NADP+ + H2O	-	?	418134	
1.14.13.160	2,3,4,5-tetramethyl-2-cyclopenten-1-one + O2 + NADPH + H+	34% conversion	Pseudomonas putida	? + NADP+ + H2O	-	?	418220	
1.14.13.160	2,3,4,5-tetramethyl-2-cyclopenten-1-one + O2 + NADPH + H+	34% conversion	Pseudomonas putida NCIMB 10007	? + NADP+ + H2O	-	?	418220	
1.14.13.160	2-cyclohexen-1-one + O2 + NADPH + H+	74% conversion	Pseudomonas putida	? + NADP+ + H2O	-	?	418229	
1.14.13.160	2-cyclohexen-1-one + O2 + NADPH + H+	74% conversion	Pseudomonas putida NCIMB 10007	? + NADP+ + H2O	-	?	418229	
1.14.13.160	2-cyclopenten-1-one + O2 + NADPH + H+	62% conversion	Pseudomonas putida	? + NADP+ + H2O	-	?	418558	
1.14.13.160	2-ethylcyclopentanone + O2 + NADPH + H+	-	Pseudomonas putida	6-ethyltetrahydro-2H-pyran-2-one + NADP+ + H2O	both enantiomers of 2-ethyl cyclohexanone are oxidized at nearly the same rate although giving a low enantiomeric ratio	?	418230	
1.14.13.160	2-ethylcyclopentanone + O2 + NADPH + H+	-	Pseudomonas putida ATCC 17453	6-ethyltetrahydro-2H-pyran-2-one + NADP+ + H2O	both enantiomers of 2-ethyl cyclohexanone are oxidized at nearly the same rate although giving a low enantiomeric ratio	?	418230	
1.14.13.160	2-methylcyclohexanone + O2 + NADPH + H+	-	Pseudomonas putida	7-methyloxepan-2-one + NADP+ + H2O	-	?	418234	
1.14.13.160	2-methylcyclohexanone + O2 + NADPH + H+	-	Pseudomonas putida ATCC 17453	7-methyloxepan-2-one + NADP+ + H2O	-	?	418234	
1.14.13.160	2-n-hexylcyclopentanone + O2 + NADPH + H+	-	Pseudomonas putida	6-hexyltetrahydro-2H-pyran-2-one + NADP+ + H2O	-	?	418235	
1.14.13.160	2-n-hexylcyclopentanone + O2 + NADPH + H+	-	Pseudomonas putida ATCC 17453	6-hexyltetrahydro-2H-pyran-2-one + NADP+ + H2O	-	?	418235	
1.14.13.160	2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetic acid + O2 + NADPH + H+	-	Pseudomonas putida	? + NADP+ + H2O	-	?	418238	
1.14.13.160	2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetic acid + O2 + NADPH + H+	-	Pseudomonas putida ATCC 17453	? + NADP+ + H2O	-	?	418238	
1.14.13.160	2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA + O2 + NADPH + H+	-	Pseudomonas putida	? + NADP+ + H2O	-	?	418239	
1.14.13.160	2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA + O2 + NADPH + H+	specific substrate	Pseudomonas putida	delta-lactone of 5-hydroxy-3,4,4-trimethyl-A2-pimelyl-CoA + NADP+ + H2O	monooxygenase reaction, catalysis of a biological Baeyer-Villiger reaction with the formation of a lactone. This lactone product is unstable and susceptible to spontaneous ring opening	?	418240	
1.14.13.160	2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA + O2 + NADPH + H+	specific substrate	Pseudomonas putida C1 / ATCC 17453	delta-lactone of 5-hydroxy-3,4,4-trimethyl-A2-pimelyl-CoA + NADP+ + H2O	monooxygenase reaction, catalysis of a biological Baeyer-Villiger reaction with the formation of a lactone. This lactone product is unstable and susceptible to spontaneous ring opening	?	418240	
1.14.13.160	2-oxocyclopentyl acetic acid + O2 + NADPH + H+	-	Pseudomonas putida	(6-oxotetrahydro-2H-pyran-2-yl)acetic acid + NADP+ + H2O	-	?	418242	
1.14.13.160	2-oxocyclopentyl ethyl acetate + O2 + NADPH + H+	-	Pseudomonas putida	ethyl (6-oxotetrahydro-2H-pyran-2-yl)acetate + NADP+ + H2O	-	?	418243	
1.14.13.160	3,5,5-trimethyl-2-cyclohexen-1-one + O2 + NADPH + H+	22% conversion	Pseudomonas putida	? + NADP+ + H2O	-	?	418268	
1.14.13.160	3,5,5-trimethyl-2-cyclohexen-1-one + O2 + NADPH + H+	22% conversion	Pseudomonas putida NCIMB 10007	? + NADP+ + H2O	-	?	418268	
1.14.13.160	3-methyl-2-cyclohexen-1-one + O2 + NADPH + H+	13% conversion	Pseudomonas putida	? + NADP+ + H2O	-	?	418275	
1.14.13.160	3-methyl-2-cyclohexen-1-one + O2 + NADPH + H+	13% conversion	Pseudomonas putida NCIMB 10007	? + NADP+ + H2O	-	?	418275	
1.14.13.160	3-methyl-2-cyclopenten-1-one + O2 + NADPH + H+	13% conversion	Pseudomonas putida	? + NADP+ + H2O	-	?	418276	
1.14.13.160	4-methylcyclohexanone + O2 + NADPH + H+	-	Pseudomonas putida	5-methyloxepan-2-one + NADP+ + H2O	-	?	418295	
1.14.13.160	bicyclo[3.2.0]hept-2-en-6-one + O2 + NADPH + H+	-	Pseudomonas putida	? + NADP+ + H2O	products are a mixture of normal to abnormal lactone at a ratio of 3:1	?	418510	
1.14.13.160	cyclobutanone + O2 + NADPH + H+	-	Pseudomonas putida	? + NADP+ + H2O	-	?	418557	
1.14.13.160	additional information	no substrate: 2,5-diketocamphane. Less than 5% of the activity with 2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA is displayed with 2-oxo-DELTA3-4,5,5-trimethylcyclo-pentenylacetyl-CoA, 2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA (hydrolyzed), 2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetate-CoA, 2,5-diketocamphane	Pseudomonas putida	?	-	?	89	
1.14.13.160	additional information	reaction of different 4-substituted cyclohexanones with small to medium substituents at the C-4 position in nearly all cases give enantiopure lactones with an excellent yield	Pseudomonas putida	?	-	?	89	
1.14.13.160	additional information	reaction of different 4-substituted cyclohexanones with small to medium substituents at the C-4 position in nearly all cases give enantiopure lactones with an excellent yield	Pseudomonas putida ATCC 17453	?	-	?	89	
1.14.13.160	additional information	no substrate: 2,5-diketocamphane. Less than 5% of the activity with 2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA is displayed with 2-oxo-DELTA3-4,5,5-trimethylcyclo-pentenylacetyl-CoA, 2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA (hydrolyzed), 2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetate-CoA, 2,5-diketocamphane	Pseudomonas putida C1 / ATCC 17453	?	-	?	89	
1.14.13.160	norcamphor + O2 + NADPH + H+	-	Pseudomonas putida	? + NADP+ + H2O	-	?	418972	
1.14.13.160	[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA + O2 + NADPH + H+	-	Pseudomonas putida	[(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA + NADP+ + H2O	-	?	419631	
1.14.13.160	[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA + O2 + NADPH + H+	-	Pseudomonas putida	[(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA + NADP+ + H2O	mass spectral analysis of the methyl ester of the product confirmes the insertion of a single oxygen atom	?	419631	
1.14.13.160	[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA + O2 + NADPH + H+	-	Pseudomonas putida C1 / ATCC 17453	[(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA + NADP+ + H2O	-	?	419631	
1.14.13.160	[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA + O2 + NADPH + H+	-	Pseudomonas putida C1 / ATCC 17453	[(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA + NADP+ + H2O	mass spectral analysis of the methyl ester of the product confirmes the insertion of a single oxygen atom	?	419631