1.13.11.50	1,1,1-trifluoro-2,4-pentanedione + O2	-	Acinetobacter johnsonii	?	-	?	386927	
1.13.11.50	1,1,1-trifluoro-pentane-2,4-dione + O2	-	Acinetobacter johnsonii	?	-	?	386928	
1.13.11.50	1,1-difluoro-2,4-pentanedione + O2	-	Acinetobacter johnsonii	?	-	?	386933	
1.13.11.50	1,1-difluoropentane-2,4-dione + O2	-	Acinetobacter johnsonii	?	-	?	425219	
1.13.11.50	1-phenyl-1,3-butanedione + O2	-	Acinetobacter johnsonii	?	-	?	353285	
1.13.11.50	1-phenylbutane-1,3-dione + O2	-	Acinetobacter johnsonii	?	-	?	375562	
1.13.11.50	2,4-dioxopentanoic acid ethyl ester + O2	-	Acinetobacter johnsonii	?	-	?	353289	
1.13.11.50	2,4-dioxopentanoic acid ethyl ester + O2	poor substrate	Acinetobacter johnsonii	?	-	?	353289	
1.13.11.50	2,4-nonadione + O2	poor substrate	Acinetobacter johnsonii	?	-	?	353287	
1.13.11.50	2,4-octanedione + O2	-	Acinetobacter johnsonii	?	-	?	353279	
1.13.11.50	2-acetylcyclohexanone + O2	-	Acinetobacter johnsonii	?	-	?	353280	
1.13.11.50	3,4-dihydroxyphenylacetate + O2	-	Acinetobacter johnsonii	?	-	?	288926	
1.13.11.50	3,5-heptanedione + O2	-	Acinetobacter johnsonii	?	-	?	353282	
1.13.11.50	3-methyl-2,4-pentanedione + O2	-	Acinetobacter johnsonii	?	-	?	353278	
1.13.11.50	3-oxobutanone + O2	-	Acinetobacter johnsonii	?	-	?	353283	
1.13.11.50	4,4-difluoro-1-phenyl-1,3-butanedione + O2	-	Acinetobacter johnsonii	?	-	?	387406	
1.13.11.50	4-hydroxy-4-methyl-2-pentanone + O2	-	Acinetobacter johnsonii	?	-	?	353284	
1.13.11.50	5,5-dimethylhexane-2,4-dione + O2	poor substrate	Acinetobacter johnsonii	?	-	?	353286	
1.13.11.50	acetylacetone + O2	-	Acinetobacter johnsonii	acetate + 2-oxopentanal	-	?	413246	
1.13.11.50	acetylcyclohexanone + O2	poor substrate	Acinetobacter johnsonii	?	-	?	353288	
1.13.11.50	ethylacetoacetate + O2	-	Acinetobacter johnsonii	?	-	?	353281	
1.13.11.50	additional information	no substrate: 4-hydroxy-4-methyl-2-pentanone, 3-oxobutanoate, quercetin, catechols, 2,4`-dihydroxyacetophenone, ascorbate	Acinetobacter johnsonii	?	-	?	89	
1.13.11.50	additional information	the catalytic reaction proceeds via one common rate-limiting step in the clevage of all substrates accepted by the enzyme	Acinetobacter johnsonii	?	-	?	89	
1.13.11.50	additional information	residues Arg80 and Tyr70 promote O2 reduction	Acinetobacter johnsonii	?	-	?	89	
1.13.11.50	additional information	the enzyme is a mononuclear non-heme iron enzymes, Dke1 active site modelling, overview	Acinetobacter johnsonii	?	-	?	89	
1.13.11.50	additional information	acetylacetone dioxygenase catalyzes the dioxygen-dependent degradation of beta-dicarbonyl compounds	Acinetobacter johnsonii	?	-	?	89	
1.13.11.50	additional information	Dke1 also performs the atypical cleavage of the alpha-keto acid, 4-hydroxyphenylpyruvate, to form 4-hydroxybenzaldehyde as product instead of the homogentisate product found for 4-hydroxyphenylpyruvate with 4-hydroxyphenylpyruvate dioxygenase, EC 1.13.11.27, analysis of the bonding of the alpha-keto acid, 4-hydroxyphenylpyruvate, to ferrous Dke1 using anaerobic Dke1, added ferrous ammonium sulfate, and 4-hydroxyphenylpyruvate at pH 7.0, overview	Acinetobacter johnsonii	?	-	?	89	
1.13.11.50	additional information	iron(II) complexes [Fe(L)(CH3CN)3](SO3CF3)2 of tris(2-pyridyl)-based ligands exhibit very similar chemical surroundings to the active site of the enzyme and mimic its functions	Paraburkholderia xenovorans	?	-	-	89	
1.13.11.50	additional information	Ni(II)-complex-adducts show regioselective oxidative cleavage of the aliphatic C-C bond using dioxygen via the substrate activation mechanism without changing the oxidation state of nickel(II) as similar to the wild type enzyme	Acinetobacter johnsonii	?	-	-	89	
1.13.11.50	pentane-2,4-dione + O2	-	Acinetobacter johnsonii	acetate + 2-oxopropanal	-	?	353277	
1.13.11.50	pentane-2,4-dione + O2	i.e. acetylacetone	Acinetobacter johnsonii	acetate + 2-oxopropanal	i.e. acetate and acetone	?	353277	
1.13.11.50	pentane-2,4-dione + O2	-	Acinetobacter johnsonii	methylglyoxal + acetate	-	?	402829	
1.13.11.50	pentane-2,4-dione + O2	-	Acinetobacter johnsonii	acetate + methylglyoxal	-	?	424963	
1.13.11.50	potassium oxalate + O2	-	Acinetobacter johnsonii	?	-	?	406430	
1.13.11.50	quercetin + O2	-	Acinetobacter johnsonii	?	-	?	289481