1.13.11.53 dioxygenation - 662091 1.13.11.53 oxidation ARD (Ni) converts aci-reductone to 3-(methylthio)propanoate, carbon monoxide, and formate, and the reaction is not part of the methionine salvage pathway cycle (off-pathway). 673849 1.13.11.53 oxidation if Ni+2 is bound in the active site, the substrate acireductone reacts with O2 to yield formate and 4-methylthio-2-ketobutyrate 675408