0.0.0.0 (+)-5-oxo-1,2-campholide = [(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetate + H+ spontaneous - 0.0.0.0 (-)-5-oxo-1,2-campholide = [(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetate + H+ spontaneous - 0.0.0.0 (2S)-2-amino-3-oxo-4-phosphonooxybutanoate + H+ = 3-amino-1-hydroxyacetone 1-phosphate + CO2 spontaneous - 0.0.0.0 (2S)-2-isopropyl-3-oxosuccinate + H+ = 4-methyl-2-oxopentanoate + CO2 spontaneous - 0.0.0.0 2,4-dihydroxy-6-[(1E,10S)-10-hydroxy-6-oxoundec-1-en-1-yl]­benzoic acid = (1E,10S)-1-(3,5-dihydroxyphenyl)-10-hydroxy­undec-1-en-6-one + CO2 - - 0.0.0.0 2-acetolactate + oxidized electron acceptor = diacetyl + CO2 + reduced electron acceptor spontaneous - 0.0.0.0 2-aminobenzoylacetyl-CoA = 4-hydroxy-2(1H)-quinolone + CoA spontaneous - 0.0.0.0 2-monoacylglycerol = 1-monoacylglycerol spontaneous - 0.0.0.0 2-oxo-6-amino-hexanoate + D-lysine = DELTA1-piperidine 2-carboxylate spontaneous - 0.0.0.0 2-oxo-6-amino-hexanoate + hydrogen peroxide = 5-aminopentanoate + H2O + CO2 spontaneous - 0.0.0.0 2-oxopent-4-enoate = cis-2-hydroxypenta-2,4-dienoate spontaneous - 0.0.0.0 3-(5-oxo-4,5-dihydro-3H-imidazol-4-yl)propanoate + H2O = 4-oxoglutaramate + formate + NH3 spontaneous - 0.0.0.0 3-hydroxy-cis,cis-muconate = 4-oxohex-2-enedioate spontaneous - 0.0.0.0 3-Sulfino-L-alanine + H2O + NAD+ = L-cysteate + NADH + H+ spontaneous - 0.0.0.0 4-(2-aminophenyl)-2,4-dioxobutanoate = kynurenate + H2O + H+ spontaneous - 0.0.0.0 4-deoxy-L-threo-5-hexosulose-uronate = 5-dehydro-4-deoxy-D-glucuronate spontaneous - 0.0.0.0 4-oxalomesaconate = 4-carboxy-2-hydroxyhexa-2,4-dienedioate spontaneous - 0.0.0.0 5-amino-2-oxopentanoate = DELTA1-pyrroline-2-carboxylate spontaneous - 0.0.0.0 5-hydroxyindole acetaldehyde + L-cysteine = 5-hydroxyindole thiazolidine carboxylate + H2O + H+ spontaneous - 0.0.0.0 7-dehydrocholesterol = previtamin D3 spontaneous - 0.0.0.0 9alpha-hydroxyandrosta-1,4-diene-3,17-dione = 3-hydroxy-9,10-secoandrosta-1,3,5(10)-triene-9,17-dione spontaneous - 0.0.0.0 artemisinate + O2 + H+ = (-)-arteannuin B + H2O spontaneous - 0.0.0.0 biotin-carboxyl-carrier protein = biotin-carboxyl-carrier protein (dimer) spontaneous - 0.0.0.0 cellobiono-1,5-lactone + H2O = cellobionate spontaneous - 0.0.0.0 cellooligosaccharide-C1-lactone + H2O = C1/C4-oxidized cello-oligosaccharides spontaneous - 0.0.0.0 D-glucaro-1,5-lactone = D-glucaro-1,4-lactone spontaneous - 0.0.0.0 D-ribofuranose = D-ribose spontaneous - 0.0.0.0 deoxyviolaceinate + O2 + H+ = deoxyviolacein + CO2 + H2O spontaneous - 0.0.0.0 enolaldehyde + H+ = methylglyoxal spontaneous - 0.0.0.0 H+ + H2O + 3-(5-oxo-4,5-dihydro-3H-imidazol-4-yl)propanoate = formyl-isoglutamine spontaneous - 0.0.0.0 H2O + 3-sulfinylpyruvate = H+ + pyruvate + sulfite spontaneous - 0.0.0.0 H2O + 4-oxoglutaramate = 2-oxoglutarate + NH3 + H+ spontaneous - 0.0.0.0 H2O + formyl-isoglutamine = isoglutamine + formate spontaneous - 0.0.0.0 H2O + L-dehydroascorbate = (4R,5S)-4,5,6-trihydroxy-2,3-dioxohexanoate spontaneous - 0.0.0.0 L-2-amino-3-oxobutanoate + H+ = aminoacetone + CO2 spontaneous - 0.0.0.0 L-2-amino-6-oxopimelate = 2,3,4,5-tetrahydrodipicolinate spontaneous - 0.0.0.0 L-ascorbate = L-dehydroascorbate spontaneous - 0.0.0.0 L-glutamate 5-semialdehyde = (S)-1-pyrroline-5-carboxylate + H+ + H2O spontaneous - 0.0.0.0 L-sorbosone = 2-dehydro-L-gulonolactone spontaneous - 0.0.0.0 neopinone = codeinone spontaneous - 0.0.0.0 previtamin D3 = Cholecalciferol spontaneous - 0.0.0.0 protodeoxyviolaceinate + O2 + H+ = prodeoxyviolacein + CO2 + H2O spontaneous - 0.0.0.0 protoviolaceinate + O2 + H+ = proviolacein + CO2 + H2O spontaneous - 0.0.0.0 ubiquinol-8 = H+ + ubiquinone spontaneous - 0.0.0.0 violaceinate + O2 + H+ = violacein + CO2 + H2O spontaneous - 0.0.0.0 [(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA = DELTA2,5-3,4,4-trimethylpimeloyl-CoA + H+ spontaneous -