2.7.8.23 1-carboxyvinyl carboxyphosphonate - 2.7.8.23 carboxyphosphonoenolpyruvate - 2.7.8.23 carboxyphosphonoenolpyruvate first natural phosphinate 2.7.8.23 carboxyphosphonoenolpyruvate biosynthetic pathway that leads to the tripeptide antibiotic bialaphos, formation of one of the two C-P bonds in bialaphos