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Literature summary extracted from

  • Sato, M.; Sakurai, N.; Suzuki, H.; Shibata, D.; Kino, K.
    Enzymatic carboxylation of hydroxystilbenes by the gamma-resorcylic acid decarboxylase from Rhizobium radiobacter WU-0108 under reverse reaction conditions (2015), J. Mol. Catal. B, 122, 348-352 .
No PubMed abstract available

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
4.1.1.103 2.67
-
gnetol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 4.46
-
resveratrol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 19.4
-
catechol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 23.1
-
resorcinol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 32.79
-
5-methylresorcinol 30°C, pH not specified in the publication Agrobacterium tumefaciens

Organism

EC Number Organism UniProt Comment Textmining
4.1.1.103 Agrobacterium tumefaciens Q60FX6
-
-
4.1.1.103 Agrobacterium tumefaciens WU-0108 Q60FX6
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.1.103 5-methylresorcinol + CO2
-
Agrobacterium tumefaciens 2,6-dihydroxy-4-methylbenzoate
-
?
4.1.1.103 5-methylresorcinol + CO2
-
Agrobacterium tumefaciens WU-0108 2,6-dihydroxy-4-methylbenzoate
-
?
4.1.1.103 catechol + CO2
-
Agrobacterium tumefaciens 2,3-dihydroxybenzoate
-
?
4.1.1.103 catechol + CO2
-
Agrobacterium tumefaciens WU-0108 2,3-dihydroxybenzoate
-
?
4.1.1.103 gnetol + CO2
-
Agrobacterium tumefaciens 2,6-dihydroxy-4-[(E)-2-(2,6-dihydroxyphenyl)ethenyl]benzoic acid
-
?
4.1.1.103 gnetol + CO2
-
Agrobacterium tumefaciens WU-0108 2,6-dihydroxy-4-[(E)-2-(2,6-dihydroxyphenyl)ethenyl]benzoic acid
-
?
4.1.1.103 additional information the enzyme introduces a carboxyl group preferentially at the 2 position of the 1,3-dihydroxybenzene moiety, with the exception of catechol, where position 3 is carboxylated. With the exception of catechol, compounds having the 1,2-dihydroxybenzene moiety in the structures such as 4-methylcatechol, butein, quercetin, fisetin, 3',4',5,7-tetrahydroxyflavone, 7,8-dihydroxyflavone and catechin give no reaction products Agrobacterium tumefaciens ?
-
?
4.1.1.103 additional information the enzyme introduces a carboxyl group preferentially at the 2 position of the 1,3-dihydroxybenzene moiety, with the exception of catechol, where position 3 is carboxylated. With the exception of catechol, compounds having the 1,2-dihydroxybenzene moiety in the structures such as 4-methylcatechol, butein, quercetin, fisetin, 3',4',5,7-tetrahydroxyflavone, 7,8-dihydroxyflavone and catechin give no reaction products Agrobacterium tumefaciens WU-0108 ?
-
?
4.1.1.103 piceatannol + CO2
-
Agrobacterium tumefaciens ?
-
?
4.1.1.103 piceatannol + CO2
-
Agrobacterium tumefaciens WU-0108 ?
-
?
4.1.1.103 resorcinol + CO2
-
Agrobacterium tumefaciens 2,6-dihydroxybenzoate
-
?
4.1.1.103 resveratrol + CO2
-
Agrobacterium tumefaciens 2,6-dihydroxy-4-[(E)-2-(4-hydroxyphenyl)ethenyl]benzoate
-
?

Synonyms

EC Number Synonyms Comment Organism
4.1.1.103 Rdc
-
Agrobacterium tumefaciens

Turnover Number [1/s]

EC Number Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
4.1.1.103 0.141
-
catechol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 0.331
-
gnetol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 0.571
-
resorcinol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 0.722
-
resveratrol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 4.98
-
5-methylresorcinol 30°C, pH not specified in the publication Agrobacterium tumefaciens

kcat/KM [mM/s]

EC Number kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
4.1.1.103 0.0073
-
catechol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 0.0247
-
resorcinol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 0.124
-
gnetol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 0.152
-
5-methylresorcinol 30°C, pH not specified in the publication Agrobacterium tumefaciens
4.1.1.103 0.162
-
resveratrol 30°C, pH not specified in the publication Agrobacterium tumefaciens