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Literature summary extracted from

  • Geertsema, E.M.; Miao, Y.; Tepper, P.G.; de Haan, P.; Zandvoort, E.; Poelarends, G.J.
    Biocatalytic Michael-type additions of acetaldehyde to nitroolefins with the proline-based enzyme 4-oxalocrotonate tautomerase yielding enantioenriched gamma-nitroaldehydes (2013), Chemistry, 19, 14407-14410.
    View publication on PubMed

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate Escherichia coli
-
(3E)-2-oxohex-3-enedioate
-
?

Organism

EC Number Organism UniProt Comment Textmining
5.3.2.6 Escherichia coli
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
5.3.2.6 (1Z)-1-(nitromethylidene)-3a,4,5,6,7,7a-hexahydro-1H-indene + acetaldehyde
-
Escherichia coli [1-(nitromethyl)-1H-inden-1-yl]acetaldehyde
-
?
5.3.2.6 (1Z)-4-methyl-1-nitropent-1-ene + acetaldehyde
-
Escherichia coli 5-methyl-3-(nitromethyl)hexanal
-
?
5.3.2.6 (2Z,4E)-2-hydroxyhexa-2,4-dienedioate
-
Escherichia coli (3E)-2-oxohex-3-enedioate
-
?
5.3.2.6 1-chloro-4-[(Z)-2-nitroethenyl]benzene + acetaldehyde
-
Escherichia coli 3-(4-chlorophenyl)-4-nitrobutanal
-
?
5.3.2.6 1-fluoro-4-[(Z)-2-nitroethenyl]benzene + acetaldehyde
-
Escherichia coli 3-(4-fluorophenyl)-4-nitrobutanal
-
?
5.3.2.6 2-(cyclopentyloxy)-1-methoxy-4-[(Z)-2-nitroethenyl]benzene + acetaldehyde
-
Escherichia coli 3-[3-(cyclopentyloxy)-4-methoxyphenyl]-4-nitrobutanal
-
?
5.3.2.6 2-methoxy-5-[(Z)-2-nitroethenyl]phenol + acetaldehyde
-
Escherichia coli 3-(3-hydroxy-4-methoxyphenyl)-4-nitrobutanal
-
?
5.3.2.6 [(Z)-2-nitroethenyl]benzene + acetaldehyde
-
Escherichia coli 4-nitro-3-phenylbutanal
-
?

Synonyms

EC Number Synonyms Comment Organism
5.3.2.6 4-OT
-
Escherichia coli
5.3.2.6 4-oxalocrotonate tautomerase
-
Escherichia coli