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Literature summary extracted from

  • Fuchs, C.; Schwab, W.
    Epoxidation, hydroxylation and aromatization is catalyzed by a peroxygenase from Solanum lycopersicum (2013), J. Mol. Catal. B, 96, 52-60.
No PubMed abstract available

Cloned(Commentary)

EC Number Cloned (Comment) Organism
1.11.2.3 expression in Saccharomyces cervisiae Solanum lycopersicum

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
1.11.2.3 0.071
-
 oleic acid pH 6.0, 40°C Solanum lycopersicum
1.11.2.3 0.078
-
 linoleic acid pH 6.0, 40°C Solanum lycopersicum
1.11.2.3 0.815
-
 trans-10,cis-12-linoleic acid pH 6.0, 40°C Solanum lycopersicum

Molecular Weight [Da]

EC Number Molecular Weight [Da] Molecular Weight Maximum [Da] Comment Organism
1.11.2.3 27900
-
 x * 27900, calculated, x * 28000, SDS-PAGE Solanum lycopersicum
1.11.2.3 28000
-
 x * 27900, calculated, x * 28000, SDS-PAGE Solanum lycopersicum

Organism

EC Number Organism UniProt Comment Textmining
1.11.2.3 Solanum lycopersicum
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.2.3 (+)-(R)-limonene + H2O2
-
 Solanum lycopersicum (R)-limonene trans-1,2-epoxide 97% of products ?
1.11.2.3 (-)-(S)-limonene + H2O2
-
 Solanum lycopersicum (S)-limonene cis-1,2-epoxide 88% of products ?
1.11.2.3 alpha-terpinene + H2O2
-
 Solanum lycopersicum cis-1,4-dihydroxy-p-menth-2-ene
-
 ?
1.11.2.3 gamma-terpinene + H2O2
-
 Solanum lycopersicum p-cymene in this reaction, hydroperoxide serves as hydrogen acceptor rather than an oxygen donor ?
1.11.2.3 linoleic acid + H2O2
-
 Solanum lycopersicum 15,16-epoxy-9,12-octadecadienoic acid + H2O 25% yield ?
1.11.2.3 additional information no substrate: geraniol Solanum lycopersicum ?
-
 ?
1.11.2.3 nerol + H2O2
-
 Solanum lycopersicum nerol-2,3-epoxide sole product ?
1.11.2.3 oleic acid + H2O2
-
 Solanum lycopersicum 9,10-epoxyoctadecanoic acid 15% yield ?
1.11.2.3 trans-10,cis-12-linoleic acid + H2O2
-
 Solanum lycopersicum 12,13-epoxy-10-octadecenoic acid epoxidation occurs only at cis-double bond ?

Subunits

EC Number Subunits Comment Organism
1.11.2.3 ? x * 27900, calculated, x * 28000, SDS-PAGE Solanum lycopersicum

Temperature Optimum [°C]

EC Number Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
1.11.2.3 40
-
-
 Solanum lycopersicum

pH Optimum

EC Number pH Optimum Minimum pH Optimum Maximum Comment Organism
1.11.2.3 6
-
-
 Solanum lycopersicum

Cofactor

EC Number Cofactor Comment Organism Structure
1.11.2.3 additional information no cofactors required Solanum lycopersicum