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Literature summary extracted from

  • Peter, S.; Kinne, M.; Ullrich, R.; Kayser, G.; Hofrichter, M.
    Epoxidation of linear, branched and cyclic alkenes catalyzed by unspecific peroxygenase (2013), Enzyme Microb. Technol., 52, 370-376.
    View publication on PubMed

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
1.11.2.1 0.069
-
 Pyridine pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 0.32
-
 Naphthalene pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 1.43
-
 1,2-dimethoxy-4-(methoxymethyl)benzene pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 4.976
-
 2-methyl-2-butene pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 18.4
-
 Cyclohexane pH 5.6, 22°C Cyclocybe aegerita

Localization

EC Number Localization Comment Organism GeneOntology No. Textmining
1.11.2.1 extracellular
-
 Cyclocybe aegerita
-
-

Organism

EC Number Organism UniProt Comment Textmining
1.11.2.1 Cyclocybe aegerita
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.2.1 (R)-(+)-limonene + H2O2
-
 Cyclocybe aegerita ? + H2O 76% epoxide products ?
1.11.2.1 (S)-(-)-limonene + H2O2
-
 Cyclocybe aegerita ? + H2O 85% epoxide products ?
1.11.2.1 1-butene + H2O2
-
 Cyclocybe aegerita but-3-en-2-ol + 2-ethyloxirane + H2O 75% epoxide product ?
1.11.2.1 1-heptene + H2O2
-
 Cyclocybe aegerita hept-1-en-3-ol + 2-pentyloxirane + H2O 88% epoxide product ?
1.11.2.1 1-hexene + H2O2
-
 Cyclocybe aegerita hex-1-en-3-ol + 2-butyloxirane + H2O 50% epoxide product ?
1.11.2.1 1-methyl-1-cyclohexene + H2O2
-
 Cyclocybe aegerita 3-methylcyclohex-3-en-1-ol + 1-methyl-7-oxabicyclo[4.1.0]heptane + H2O 70% epoxide product ?
1.11.2.1 1-octene + H2O2
-
 Cyclocybe aegerita oct-1-en-3-ol + 2-hexyloxirane + H2O 55% epoxide product ?
1.11.2.1 1-pentene + H2O2
-
 Cyclocybe aegerita pent-1-en-3-ol + 2-propyloxirane + H2O 31% epoxide product ?
1.11.2.1 2,3-dimethyl-2-butene + H2O2
-
 Cyclocybe aegerita 2,2,3,3-tetramethyloxirane + H2O sole product ?
1.11.2.1 2-methyl-2-butene + H2O2
-
 Cyclocybe aegerita 2,2,3-trimethyloxirane + H2O sole product ?
1.11.2.1 2-methylpropene + H2O2
-
 Cyclocybe aegerita 2,2-dimethyloxirane + H2O sole product ?
1.11.2.1 4-methyl-1-cyclohexene + H2O2
-
 Cyclocybe aegerita 3-methyl-7-oxabicyclo[4.1.0]heptane + 6-methylcyclohex-2-en-1-ol + H2O 70% epoxide product ?
1.11.2.1 cis-2-butene + H2O2
-
 Cyclocybe aegerita 2,3-dimethyloxirane + H2O sole product ?
1.11.2.1 cyclohexane + H2O2
-
 Cyclocybe aegerita ? + H2O
-
 ?
1.11.2.1 cyclohexene + H2O2
-
 Cyclocybe aegerita cyclohex-2-en-1-ol + 7-oxabicyclo[4.1.0]heptane + H2O 55% epoxide product ?
1.11.2.1 methyl 3,4-dimethoxybenzyl ether + H2O2
-
 Cyclocybe aegerita 3,4-dimethoxybenzaldehyde + methanol + H2O
-
 ?
1.11.2.1 naphthalene + H2O2
-
 Cyclocybe aegerita naphthalene 1,2-oxide + H2O
-
 ?
1.11.2.1 propene + H2O2
-
 Cyclocybe aegerita 2-methyloxirane + H2O 100% epoxide product ?
1.11.2.1 pyridine + H2O2
-
 Cyclocybe aegerita pyridine N-oxide + H2O
-
 ?
1.11.2.1 trans-2-butene + H2O2
-
 Cyclocybe aegerita 2,3-dimethyloxirane + H2O sole product ?

Turnover Number [1/s]

EC Number Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
1.11.2.1 0.21
-
 Pyridine pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 37
-
 Cyclohexane pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 166
-
 Naphthalene pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 720
-
 1,2-dimethoxy-4-(methoxymethyl)benzene pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 1257
-
 2-methyl-2-butene pH 5.6, 22°C Cyclocybe aegerita

kcat/KM [mM/s]

EC Number kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
1.11.2.1 2
-
 Cyclohexane pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 3
-
 Pyridine pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 250
-
 2-methyl-2-butene pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 500
-
 1,2-dimethoxy-4-(methoxymethyl)benzene pH 5.6, 22°C Cyclocybe aegerita
1.11.2.1 520
-
 Naphthalene pH 5.6, 22°C Cyclocybe aegerita