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Literature summary extracted from

  • van Hellemond, E.W.; Janssen, D.B.; Fraaije, M.W.
    Discovery of a novel styrene monooxygenase originating from the metagenome (2007), Appl. Environ. Microbiol., 73, 5832-5839.
    View publication on PubMedView publication on EuropePMC

Cloned(Commentary)

EC Number Cloned (Comment) Organism
1.14.14.11 expression in Escherichia coli. 50% sequence identity with styrene monooxygenases from pseudomonads uncultured bacterium

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.14.14.11 styrene + FADH2 + O2 uncultured bacterium
-
 (S)-2-phenyloxirane + FAD + H2O
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
1.14.14.11 uncultured bacterium A8BQ92
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.14.11 2-chlorostyrene + FADH2 + O2 2-chloro-(S)-styrene oxide is formed with 94% enantiomeric excess uncultured bacterium (2S)-2-(2-chlorophenyl)oxirane + FAD + H2O
-
 ?
1.14.14.11 3-chlorostyrene + FADH2 + O2 2-chloro-(S)-styrene oxide is formed with more than 99% enantiomeric excess uncultured bacterium (2S)-2-(3-chlorophenyl)oxirane + FAD + H2O
-
 ?
1.14.14.11 4-chlorostyrene + FADH2 + O2 2-chloro-(S)-styrene oxide is formed with more than 99% enantiomeric excess uncultured bacterium (2S)-2-(4-chlorophenyl)oxirane + FAD + H2O
-
 ?
1.14.14.11 additional information the enzyme also catalyzes sulfoxidation of aromatic sulfides uncultured bacterium ?
-
 ?
1.14.14.11 styrene + FADH2 + O2
-
 uncultured bacterium (S)-2-phenyloxirane + FAD + H2O
-
 ?
1.14.14.11 styrene + FADH2 + O2 (S)-styrene oxide is formed with more than 99% enantiomeric excess uncultured bacterium (S)-2-phenyloxirane + FAD + H2O
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.14.14.11 SmoA
-
 uncultured bacterium