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Literature summary extracted from

  • Olsen, M.T.; Bruschi, M.; De Gioia, L.; Rauchfuss, T.B.; Wilson, S.R.
    Nitrosyl derivatives of diiron(I) dithiolates mimic the structure and Lewis acidity of the [FeFe]-hydrogenase active site (2008), J. Am. Chem. Soc., 130, 12021-12030.
    View publication on PubMedView publication on EuropePMC

Activating Compound

EC Number Activating Compound Comment Organism Structure
1.12.99.6 additional information nitrosyl complexes reduce at potentials that are ca. 1 V milder than their carbonyl counterparts, NO+ forms diiron dithiolates that are not isostructural with the corresponding carbonyl complexes and that display enhanced Lewis acidity synthetic construct

Inhibitors

EC Number Inhibitors Comment Organism Structure
1.12.99.6 CO the bis(PMe3) nitrosyl complexes readily undergo CO substitution to give the (PMe3)3 derivatives synthetic construct

Organism

EC Number Organism UniProt Comment Textmining
1.12.99.6 synthetic construct
-
-
-

Synonyms

EC Number Synonyms Comment Organism
1.12.99.6 [FeFe]-hydrogenase
-
synthetic construct