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Literature summary extracted from

  • Thiele, B.; Rieder, O.; Golding, B.T.; Mueller, M.; Boll, M.
    Mechanism of enzymatic Birch reduction: stereochemical course and exchange reactions of benzoyl-CoA reductase (2008), J. Am. Chem. Soc., 130, 14050-14051.
    View publication on PubMed

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
1.3.7.8 benzoyl-CoA + reduced ferredoxin + ATP + H2O Thauera aromatica
-
 cyclohexa-1,5-diene-1-carboxyl-CoA + oxidized ferredoxin + ADP + phosphate
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
1.3.7.8 Thauera aromatica
-
-
-
4.2.1.100 Thauera aromatica o87873
-
-

Purification (Commentary)

EC Number Purification (Comment) Organism
1.3.7.8
-
 Thauera aromatica

Specific Activity [micromol/min/mg]

EC Number Specific Activity Minimum [µmol/min/mg] Specific Activity Maximum [µmol/min/mg] Comment Organism
1.3.7.8 0.25
-
-
 Thauera aromatica

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.3.7.8 benzoyl-CoA + reduced ferredoxin + ATP + H2O
-
 Thauera aromatica cyclohexa-1,5-diene-1-carboxyl-CoA + oxidized ferredoxin + ADP + phosphate
-
 ?
4.2.1.100 cyclohexa-1,5-dienecarbonyl-CoA + H2O trans-1,4 water addition, stereochemistry of 6-hydroxycyclohex-1-ene-1-carboxyl-CoA by NMR analysis Thauera aromatica 6-hydroxycyclohex-1-ene-1-carbonyl-CoA
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.3.7.8 benzoyl-CoA reductase
-
 Thauera aromatica
4.2.1.100 DCH
-
 Thauera aromatica
4.2.1.100 dienoyl-CoA hydratase
-
 Thauera aromatica

Cofactor

EC Number Cofactor Comment Organism Structure
1.3.7.8 Ferredoxin
-
 Thauera aromatica